LUBRICANTS KNOWLEDGE



BASIC

Lubricant:

A lubricant is a substance, usually organic, introduced to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, transporting foreign particles, or heating or cooling the surfaces. The property of reducing friction is known as lubricity.

Properties

A good lubricant generally possesses the following characteristics:

  • A high boiling point and low freezing point (in order to stay liquid within a wide range of temperature)
  • A high viscosity index
  • Thermal stability
  • Hydraulic stability
  • Demulsibility
  • Corrosion prevention
  • A high resistance to oxidation

Formulation

Typically lubricants contain 90% base oil (most often petroleum fractions, called mineral oils) and less than 10% additives. Vegetable oils or synthetic liquids such as hydrogenated polyolefins, esters, silicones, fluorocarbons and many others are sometimes used as base oils. Additives deliver reduced friction and wear, increased viscosity, improved viscosity index, resistance to corrosion and oxidation, aging or contamination, etc.

Mineral oils

The term "mineral oil" is used to refer to lubricating base oils derived from crude oil. The American Petroleum Institute (API) designates several types of lubricant base oil:

  • Group I – Saturates < 90% and/or sulfur > 0.03%, and Society of Automotive Engineers (SAE) viscosity index (VI) of 80 to 120. Manufactured by solvent extraction, solvent or catalytic dewaxing, and hydro-finishing processes. Common Group I base oil are 150SN (solvent neutral), 500SN, and 150BS (brightstock)
  • Group II – Saturates < 90% and sulfur > 0.03%, and SAE viscosity index of 80 to 120. Manufactured by hydrocracking and solvent or catalytic dewaxing processes. Group II base oil has superior anti-oxidation properties since virtually all hydrocarbon molecules are saturated. It has water-white color.
  • Group III – Saturates < 90%, sulfur > 0.03%, and SAE viscosity index over 120. Manufactured by special processes such as isohydromerization. Can be manufactured from base oil or slax wax from dewaxing process.
  • Group IV 3 b – Polyalphaolefins (PAO)
  • Group V – All others not included above such as naphthenics, PAG, l 80esters.

The lubricant industry commonly extends this group terminology to include:

  • Group I+ with a viscosity index of 103–108
  • Group II+ with a viscosity index of 113–119
  • Group III+ with a viscosity index of at least 140

Can also be classified into three categories depending on the prevailing compositions:

  • Paraffinic
  • Naphthenic
  • Aromatic

Synthetic oils

Petroleum-derived lubricant can also be produced using synthetic hydrocarbons (derived ultimately from petroleum).

These include:

  • Polyalpha-olefin (PAO)
  • Synthetic esters
  • Polyalkylene glycols (PAG)
  • Phosphate esters
  • Alkylated naphthalenes (AN)
  • Silicate esters
  • Ionic fluids
  • Multiply alkylated cyclopentanes (MAC)

Additives

A large number of additives are used to impart performance characteristics to the lubricants. Modern automotive lubricants contain as many as ten additives, comprising up to 20% of the lubricant, the main families of additives are:

  • Pour point depressants are compounds that prevent crystallization of waxes. Long chain alkylbenzenes adhere to small crystallites of wax, preventing crystal growth.
  • Anti-foaming agents are typically silicone compounds which lower surface tension in order to discourage foam formation.
  • Viscosity index improvers (VIIs) are compounds that allow lubricants to remain viscous at higher temperatures. Typical VIIs are polyacrylates and butadiene.
  • Antioxidants suppress the rate of oxidative degradation of the hydrocarbon molecules within the lubricant. At low temperatures, free radical inhibitors such as hindered phenols are used, e.g. butylated hydroxytoluene. At temperatures >90°C, where the metals catalyze the oxidation process, dithiophosphates are more useful. In the latter application the additives are called metal deactivators.
  • Detergents ensure the cleanliness of engine components by preventing the formation of deposits on contact surfaces at high temperatures.
  • Corrosion inhibitors (rust inhibitors) are usually alkaline materials, such as alkylsulfonate salts, that absorb acids that would corrode metal parts.
  • Anti-wear additives form protective 'tribofilms' on metal parts, suppressing wear. They come in two classes depending on the strength with which they bind to the surface. Popular examples include phosphate esters and zinc dithiophosphates.
  • Extreme pressure (anti-scuffing) additives form protective films on sliding metal parts. These agents are often sulfur compounds, such as dithiophosphates.
  • Friction modifiers reduce friction and wear, particularly in the boundary lubrication regime where surfaces come into direct contact.

Biolubricant

Biolubricants are derived from vegetable oils and other renewable sources. They usually are triglyceride esters (fats obtained from plants and animals. For lubricant base oil use, the vegetable derived materials are preferred. Common ones include high oleic canola oil, castor oil, palm oil, sunflower seed oil and rapeseed oil from vegetable, and tall oil from tree sources. Many vegetable oils are often hydrolyzed to yield the acids which are subsequently combined selectively to form specialist synthetic esters. Other naturally derived lubricants include lanolin (wool grease, a natural water repellent).

Whale oil was a historically important lubricant, with some uses up to the latter part of the 20th century as a friction modifier additive for automatic transmission fluid.

In 2008, the biolubricant market was around 1% of UK lubricant sales in a total lubricant market of 840,000 tonnes/year.

Solid lubricants

  • PTFE : polytetrafluoroethylene (PTFE) is typically used as a coating layer on, for example, cooking utensils to provide a non-stick surface. Its usable temperature range up to 350 °C and chemical inertness make it a useful additive in special greases. Under extreme pressures, PTFE powder or solids is of little value as it is soft and flows away from the area of contact. Ceramic or metal or alloy lubricants must be used then.[6]
  • Inorganic solids : Graphite, hexagonal boron nitride, molybdenum disulfide and tungsten disulfide are examples of solid lubricants. Some retain their lubricity to very high temperatures. The use of some such materials is sometimes restricted by their poor resistance to oxidation (e.g., molybdenum disulfide degrades above 350 °C in air, but 1100 °C in reducing environments.
  • Metal/alloy : Metal alloys, composites and pure metals can be used as grease additives or the sole constituents of sliding surfaces and bearings. Cadmium and gold are used for plating surfaces which gives them good corrosion resistance and sliding properties, Lead, tin, zinc alloys and various bronze alloys are used as sliding bearings, or their powder can be used to lubricate sliding surfaces alone.

Wikipedia. Lubricant, from https://en.wikipedia.org/wiki/Lubricant